ATTEMPTED SYNTHESIS OF PHOSPHORUS CRYPTANDS

ATTEMPTED SYNTHESIS OF PHOSPHORUS CRYPTANDS

Reaction of the aldehyde monoacetal OHC-C≡C-CH(OEt), 4 with the phosphorhydrazide (S)P[N(CH 3 )NH 2 ] 3 3 leads to the phosphorhydrazide (S)P[N(CH 3 )N=CH-C≡C- CH(OEt) 2 ] 3 5. Formolysis of 5 yields the new multifunctionalized 1.11.11′ phosphotrihydrazide (S)P[N(CH 3 )-N=CH-C≡C-CHO] 3 6. Treatment...

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1991-02, Vol.56 (1-4), p.123-127
Hauptverfasser: Badri, Meryam, Caminade, Anne-Marie, Majoral, Jean Pierre, Gorgues, Alain
Format: Artikel
Sprache:eng
Schlagworte:
1.2.1.3, 1.4 Dialdehydes
Applied sciences
Exact sciences and technology
Organic polymers
Phosphorus Cryptands
Phosphorus Macrocycles
Phosphotrialdehyde
Phosphotrihydrazides
Physicochemistry of polymers
Polymers
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Zusammenfassung:Reaction of the aldehyde monoacetal OHC-C≡C-CH(OEt), 4 with the phosphorhydrazide (S)P[N(CH 3 )NH 2 ] 3 3 leads to the phosphorhydrazide (S)P[N(CH 3 )N=CH-C≡C- CH(OEt) 2 ] 3 5. Formolysis of 5 yields the new multifunctionalized 1.11.11′ phosphotrihydrazide (S)P[N(CH 3 )-N=CH-C≡C-CHO] 3 6. Treatment of 3 either with 6 or with various 1.3 or 1.4 dialdehydes does not afford phosphorus cryptands but leads to phosphorus polymers possessing macrocyclic phosphorus sequencies.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509108038074