The Electronic Nature of the P=C Bond

The influence of substituents at the carbon of the P=C bond of about 60 phosphaalkenes was investigated by 31 P NMR spectroscopy. The P=C system is characterized as electronwithdrawing. All compounds were found to be configurationally stable.

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Veröffentlicht in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 1990-05, Vol.49-50 (1-4), p.281-284
Hauptverfasser: Does, Thomas Van Der, Bickelhaupt, Friedrich
Format: Artikel
Sprache:eng
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Zusammenfassung:The influence of substituents at the carbon of the P=C bond of about 60 phosphaalkenes was investigated by 31 P NMR spectroscopy. The P=C system is characterized as electronwithdrawing. All compounds were found to be configurationally stable.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426509008038960