Synthesis of Some 2′,3′-Didehydro-2′,3′-dideoxynucleosides and 2′,3′- dideoxynucleosides

Synthesis of Some 2′,3′-Didehydro-2′,3′-dideoxynucleosides and 2′,3′- dideoxynucleosides

2′,3′-Didehydro-2′,3′-dideoxyformycin A (4), 2′,3′-dideoxyformycin A (11), 2′,3′-dideoxytubercidin (12) and 2′,3′-dideoxy-3-deazaadenosine (19) were synthesised via a free radical β-elimination of bromo and phenoxythiocarbonyl groups or by deoxygenation of appropriate 2′ and 3′-deoxy counterparts....

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Veröffentlicht in:Nucleosides & nucleotides 1991-01, Vol.10 (1-3), p.491-493
1. Verfasser: Serafinowski, Pawel
Format: Artikel
Sprache:eng
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Zusammenfassung:2′,3′-Didehydro-2′,3′-dideoxyformycin A (4), 2′,3′-dideoxyformycin A (11), 2′,3′-dideoxytubercidin (12) and 2′,3′-dideoxy-3-deazaadenosine (19) were synthesised via a free radical β-elimination of bromo and phenoxythiocarbonyl groups or by deoxygenation of appropriate 2′ and 3′-deoxy counterparts.
ISSN:0732-8311
DOI:10.1080/07328319108046504