The Photooxidation of Some Anthryl Phosphorus Compounds

The photo-oxidation of anthryl phosphorus compounds occurs via a Type II process. All products observed can be accounted for by involving a 9, 10-endoperoxide, which may subsequently fragment, resulting in cleavage of the phosphorus moiety from the anthracene nucleus.

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Veröffentlicht in:Phosphorus and sulfur and the related elements 1983-12, Vol.18 (1-3), p.225-228
Hauptverfasser: Buckland, Simon J., Davidson, R. Stephen
Format: Artikel
Sprache:eng
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Zusammenfassung:The photo-oxidation of anthryl phosphorus compounds occurs via a Type II process. All products observed can be accounted for by involving a 9, 10-endoperoxide, which may subsequently fragment, resulting in cleavage of the phosphorus moiety from the anthracene nucleus.
ISSN:0308-664X
DOI:10.1080/03086648308076007