SOME ASPECTS OF COMPETITIVE COORDINATION OF β-DIKETONES AND NITROGEN-CONTAINING LIGANDS

SOME ASPECTS OF COMPETITIVE COORDINATION OF β-DIKETONES AND NITROGEN-CONTAINING LIGANDS

Different coordination modes for transition metal atoms with typical chelating ligands such as β-diketones, o-oxyazomethines, azoles and azines are reviewed. Factors influencing the coordination such as ligand structure, methods and conditions of the synthesis, nature of solvent and specific hard-so...

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Veröffentlicht in:Journal of coordination chemistry 1999-02, Vol.46 (4), p.365-395
Hauptverfasser: Garnovskii, Alexander D., Kharisov, Boris I., Blanco, Leonor M., Garnovskii, Dmitry A., Burlov, Anatoly S., Vasilchenko, Igor S., Bondarenko, Gennady I.
Format: Artikel
Sprache:eng
Schlagworte:
adducts
chelates
non-traditional coordinations
o-oxyazomethinic ligands
β-Diketones
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Zusammenfassung:Different coordination modes for transition metal atoms with typical chelating ligands such as β-diketones, o-oxyazomethines, azoles and azines are reviewed. Factors influencing the coordination such as ligand structure, methods and conditions of the synthesis, nature of solvent and specific hard-soft interactions are emphasized.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958979908054903