Synthesis and Characterization of [(η6-arene)Ru(R3P)Cl2] Complexes
The synthesis and characterization of the complexes: [(η 6 -arene)Ru(R 3 P)Cl 2 ], [(arene = C 6 H 6 , MeC 6 H 5 , p-MeC 6 H 4 , CHMe 2 , and C 6 Me 6 ; R 3 P = Ph 2 ,PCH˭CH 2 (DPVP); PhP(CH˭CH 2 ) 2 (DVPP), Ph 2 PCH 2 CH˭CH 2 (ADPP); and l-phenyl-3,4-dimethylphosphole (DMPP)] are described. These c...
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| Veröffentlicht in: | Synthesis and reactivity in inorganic and metal-organic chemistry 2000-03, Vol.30 (3), p.379-407 |
|---|---|
| Hauptverfasser: | , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The synthesis and characterization of the complexes: [(η
6
-arene)Ru(R
3
P)Cl
2
], [(arene = C
6
H
6
, MeC
6
H
5
, p-MeC
6
H
4
, CHMe
2
, and C
6
Me
6
; R
3
P = Ph
2
,PCH˭CH
2
(DPVP); PhP(CH˭CH
2
)
2
(DVPP), Ph
2
PCH
2
CH˭CH
2
(ADPP); and l-phenyl-3,4-dimethylphosphole (DMPP)] are described. These complexes have been characterized by elemental analyses, physical properties,
1
H,
13
C{
1
H}, and
31
P{
1
H} NMR spectroscopy, infrared spectroscopy, cyclic voltammetry and in most cases by-X-ray crystallography. |
|---|---|
| ISSN: | 0094-5714 1532-2440 |
| DOI: | 10.1080/00945710009351770 |