Synthesis and Investigation of Properties of Vinylcontaining Silyllactams and Their Copolymers

The interactions of vinylorganochlorsilanes with lactams (ε-caprolactam, γ-pyrolidon) have been studied. New vinylcontaining N-silyllactams and aminosilanes have been synthesized and characterized, and the copolymerization reactions of N-vinyl-silyllactams with organic vinyl monomers (styrol, methyl...

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Veröffentlicht in:International journal of polymeric materials 1992-09, Vol.18 (1-2), p.95-104
Hauptverfasser: Lekishvili, N. G., Khananashvili, L. M., Akhobadze, D. Sh, Rubinstein, G. M., Gogobershvili, K. M.
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Sprache:eng
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Zusammenfassung:The interactions of vinylorganochlorsilanes with lactams (ε-caprolactam, γ-pyrolidon) have been studied. New vinylcontaining N-silyllactams and aminosilanes have been synthesized and characterized, and the copolymerization reactions of N-vinyl-silyllactams with organic vinyl monomers (styrol, methyl- and butylmethacrylate, fluorine and silicium-containing methacrylate) have been carried out. The obtained copolymers were investigated by element analysis, IR- and NMR spectroscopic analyses, MMD. The results of these investigations have shown that the introduction of silicium-containing monomers into the main chain of polystyrols and polyacrylates causes their chemical modifications with improving thermostability, processability, etc.
ISSN:0091-4037
1563-535X
DOI:10.1080/00914039208034816