The Improvement of Compatibility in Glass Fiber Reinforced PA6/PP Blends

Rheological properties (melt flow index and melt stability), mechanical properties (tensile strength, flexural strength and impact) of polyamide (PA6) polypropylene (PP) blends were investigated. Influence of potential compatibilizors: 4,4′-diphenyhnethane carbodiimide (OCDI), 4,4′-diphenylmethane b...

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Veröffentlicht in:International journal of polymeric materials 2000-07, Vol.46 (3-4), p.641-654
Hauptverfasser: Andreeva, M. B., Novotortzeva, T. N., Kalugina, E. V., Tochin, V. A., Gurinovich, L. N., Andreeva, T. I., Kalinina, I. G., Gumargalieva, K. Z., Zaikov, G. E.
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Sprache:eng
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Zusammenfassung:Rheological properties (melt flow index and melt stability), mechanical properties (tensile strength, flexural strength and impact) of polyamide (PA6) polypropylene (PP) blends were investigated. Influence of potential compatibilizors: 4,4′-diphenyhnethane carbodiimide (OCDI), 4,4′-diphenylmethane bismaleimide (BMI) and 2,2′-(1,4-pheaylene)-bisoxazoline (OX) on mechanical properties and thermostability of initial and glass reinforced polymer blends was also investigated too. We tried to study the structure of glass fiber reinforced composites by mercury intrusion porosimitry. The influence of compatibilizors on molecular weight of PA6 was studied by GPC, on chemical structure of blends was investigated by NMR and IR-spectroscopy. Addition of OCDI and OX (chain extenders) preserves the product formation as the react with the active and carbonyl groups of PA6. BMI has lower reactivity. Grafting of BMI to PP chains improves compatibility in PA6/PP blend and increases PP adhesion to glass fiber.
ISSN:0091-4037
1563-535X
DOI:10.1080/00914030008033902