Iodohydrins: An Easy Route to Epoxides from Alkenes
The preparation of epoxides is efficiently achieved by reaction of alkenes with I 2 in aqueous dioxane in the presence of Cu(OAc) 2 .H 2 O followed by treatment with KOH in a biphasic system (H 2 O/ether/pentane).
Gespeichert in:
| Veröffentlicht in: | Synthetic communications 1998-02, Vol.28 (3), p.559-572 |
|---|---|
| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | The preparation of epoxides is efficiently achieved by reaction of alkenes with I
2
in aqueous dioxane in the presence of Cu(OAc)
2
.H
2
O followed by treatment with KOH in a biphasic system (H
2
O/ether/pentane). |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397919808005111 |