Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

Selective and High-Yield Electrosynthesis of (Silyl and Silanylene 1-Methylpyrroles) from 1-Methylpyrrole Bromides

The sacrificial anode technique proved to be efficient for the selective and competitive silylation of 1-methylpyrrole bromides with trimethylchlorosilane and diorganodichlorosilanes. Linear and cyclic alternated 1-methyl-pyrrolylene-silanylene oligomers were obtained in good to high yields.

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Veröffentlicht in:Synthetic communications 1998-09, Vol.28 (18), p.3403-3414
Hauptverfasser: Moreau, C., Serein-Spirau, F., Bordeau, M., Biran, C.
Format: Artikel
Sprache:eng
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Zusammenfassung:The sacrificial anode technique proved to be efficient for the selective and competitive silylation of 1-methylpyrrole bromides with trimethylchlorosilane and diorganodichlorosilanes. Linear and cyclic alternated 1-methyl-pyrrolylene-silanylene oligomers were obtained in good to high yields.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919808004448