Low-Valent Titanium Induced Reductive Cyclization of 4,4-Dicyano-1,3-diaryl-1-butanone. Application to the Synthesis of 1-Amino-2-cyanocyclopentene Derivatives
Titanium tetrachloride was reduced by zinc powder in THF to produce low-valent titanium which reacted with 4,4-dicyano-1,3-diaryl-1-buanone to give the derivatives of 1-amino-2-cyanocyclopentene.
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Veröffentlicht in: | Synthetic communications 1997-12, Vol.27 (23), p.4121-4129 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | Titanium tetrachloride was reduced by zinc powder in THF to produce low-valent titanium which reacted with 4,4-dicyano-1,3-diaryl-1-buanone to give the derivatives of 1-amino-2-cyanocyclopentene. |
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ISSN: | 0039-7911 1532-2432 |
DOI: | 10.1080/00397919708005460 |