A Convenient Method of Meta-Directing Nitration of 3-Substituted Phenol by Lanthanide (III) Nitrates

Abstract : Thirteen compounds of 3-substituted phenols were nitrated by lanthanide(III) nitrates in a solution of ethyl acetate. Whether the substituents were ortho-, para-directing groups or meta-directing groups, only one kind nitrated product, 3-substituted-5-nitropenol, and its intermediate were...

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Veröffentlicht in:Synthetic communications 1997-08, Vol.27 (16), p.2793-2797
Hauptverfasser: Gu, Shangxiang, Jing, Huanwang, Wu, Jigui, Liang, Yongmin
Format: Artikel
Sprache:eng
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Zusammenfassung:Abstract : Thirteen compounds of 3-substituted phenols were nitrated by lanthanide(III) nitrates in a solution of ethyl acetate. Whether the substituents were ortho-, para-directing groups or meta-directing groups, only one kind nitrated product, 3-substituted-5-nitropenol, and its intermediate were obtained respectively.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004154