Synthesis of Dialkoxydimethylsilanes and 2,2-Dimethyl-1,3-dioxa- 1-Silacyclo Compounds

Synthesis of Dialkoxydimethylsilanes and 2,2-Dimethyl-1,3-dioxa- 1-Silacyclo Compounds

In the presence of iodine, magnesium reacts with alcohols to give magnesium alkoxides, which are treated with octamethylcyclotetrasiloxane to produce dialkoxydimethylsilanes. Similarly, magnesium reacts with 1,3, 1,4 and 1,5 diols and then with octamethylcyclotetrasiloxane, producing 2, 2-dimethyl-1...

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Veröffentlicht in:Synthetic communications 1997-07, Vol.27 (14), p.2527-2532
Hauptverfasser: Lin, Ji-Mao, Zhou, Ai-Min, Zhang, Hui, Hao, Ai-You
Format: Artikel
Sprache:eng
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Zusammenfassung:In the presence of iodine, magnesium reacts with alcohols to give magnesium alkoxides, which are treated with octamethylcyclotetrasiloxane to produce dialkoxydimethylsilanes. Similarly, magnesium reacts with 1,3, 1,4 and 1,5 diols and then with octamethylcyclotetrasiloxane, producing 2, 2-dimethyl-1, 3-dioxa-2-silacyclo compounds.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397919708004117