A Convenient and Improved Procedure for the Cyanation of Enamines and 1,3-Dicarbonyl Compounds
The direct cyanation of enamines 2a-f using acylsubstituted cyanatobenzenes 1a-c and cyanatoanthraquinone 1d furnishes β-cyanoenamines 3a-f which upon hydrolysis afford the cyanoketones 4a,b. 2-Cyano-1,3-diketones 6a-c are obtained starting from compounds 5a-c and 1.
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| Veröffentlicht in: | Synthetic communications 1994-12, Vol.24 (22), p.3241-3248 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The direct cyanation of enamines 2a-f using acylsubstituted cyanatobenzenes 1a-c and cyanatoanthraquinone 1d furnishes β-cyanoenamines 3a-f which upon hydrolysis afford the cyanoketones 4a,b. 2-Cyano-1,3-diketones 6a-c are obtained starting from compounds 5a-c and 1. |
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| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397919408010246 |