High Yield Synthesis of α Propargylic Acrylic Ester: A General Access to α Substituted Acrylic Esters

A heterogeneous mediated, high yield, monopropargyla-tion of ethyl benzoylacetate followed by a methyle-nation reaction using a formaldehyde addition-benzoyl elimination mechanism is described. This useful method is extended to the synthesis of a substituted acrylic esters.

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Veröffentlicht in:Synthetic communications 1988-08, Vol.18 (11), p.1213-1223
Hauptverfasser: Queignec, René, Kirschleger, Bernard, Lambert, François, Aboutaj, Mohammed
Format: Artikel
Sprache:eng
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Zusammenfassung:A heterogeneous mediated, high yield, monopropargyla-tion of ethyl benzoylacetate followed by a methyle-nation reaction using a formaldehyde addition-benzoyl elimination mechanism is described. This useful method is extended to the synthesis of a substituted acrylic esters.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397918808060913