An Efficient Synthetic Sequence for Sondheimer's Onocerin Intermediate. A Clarification
The purpose of this communication is to describe an efficient, low-cost, large-scale preparation of decalone 2 which was first prepared by Sondheimer and Elad in eleven steps from the Wieland-Mischer ketone 1 . Later, this route (1←2) was modified by several groups but all these procedures have suff...
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Veröffentlicht in: | Synthetic communications 1985-03, Vol.15 (4), p.341-354 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The purpose of this communication is to describe an efficient, low-cost, large-scale preparation of decalone 2 which was first prepared by Sondheimer and Elad in eleven steps from the Wieland-Mischer ketone
1
. Later, this route (1←2) was modified by several groups but all these procedures have suffered from the dis- advantage that the catalytic hydrogenation of the double bond present in the various intermediates was not stereospecific. |
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ISSN: | 0039-7911 1532-2432 |
DOI: | 10.1080/00397918508063809 |