The Electrochemical Reductive Coupling of Mono-Enol Ethers of β-Diketones
The one electron electrochemical reduction of α,β-unsaturated ketones 2 is a useful method of establishing carbon to carbon bonds. For example 3 , it has been utilized in an intramolecular coupling to generate the perhydrophenanthrene ring system in the reduction of 1 to 2:
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| Veröffentlicht in: | Synthetic communications 1981-01, Vol.11 (1), p.55-59 |
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| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The one electron electrochemical reduction of α,β-unsaturated ketones
2
is a useful method of establishing carbon to carbon bonds. For example
3
, it has been utilized in an intramolecular coupling to generate the perhydrophenanthrene ring system in the reduction of 1 to 2: |
|---|---|
| ISSN: | 0039-7911 1532-2432 |
| DOI: | 10.1080/00397918108064282 |