A Mild Method for the Esterification of Fatty Acids

In conjunction with a synthetic problem, we were in need of a method for the stoichiometric esterification of fatty acids, containing the aqueous acid labile tert -butyl dimethylsilyloxy group (OTBS), with a variety of alcohols. It has been reported 2 that fatty acids form acylureas in the presence...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Synthetic communications 1979-01, Vol.9 (6), p.539-543
Hauptverfasser: Ziegler, Frederick E., Berger, Gregory D.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In conjunction with a synthetic problem, we were in need of a method for the stoichiometric esterification of fatty acids, containing the aqueous acid labile tert -butyl dimethylsilyloxy group (OTBS), with a variety of alcohols. It has been reported 2 that fatty acids form acylureas in the presence of dicyclo-hexylcarbodiimide (DCC) and methanol 3 without esterification.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397917908060958