The Application of Ceric Ammonium Nitrate in the Synthesis of Carbodiazones

The preparation of bisaryl carbodiazone compounds from the aryl substituted carbazides with Ceric Ammonium Nitrate (CAN) has been reported for the first time in excellent yields (80-91%). This method only needs simple instruments and short reaction time. A possible mechanism has been suggested.

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Veröffentlicht in:Synthetic communications 2000-04, Vol.30 (10), p.1807-1812
Hauptverfasser: Xiao, Jun-Ping, Wang, Yu-Lu, Jia, Xue-Shun, Wang, Xiao-Yang, Wang, Hong
Format: Artikel
Sprache:eng
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Zusammenfassung:The preparation of bisaryl carbodiazone compounds from the aryl substituted carbazides with Ceric Ammonium Nitrate (CAN) has been reported for the first time in excellent yields (80-91%). This method only needs simple instruments and short reaction time. A possible mechanism has been suggested.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910008087226