Synthesis of 3,4-Bis (4′-Methylphenyl) Thieno [2,3-b]Thiophene: First Example of Peri-Diaryl Thienothiophene

3,4-bis(4′-methylphenyl) thienothiophene, the first example of peri-(3,4) diaryl thienothiophene has been synthesized by a sequence involving preparation of ketene dithioacetal, Dieckmann type cyclization, ester hydrolysis and decarboxylation.

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Veröffentlicht in:Synthetic communications 2000-04, Vol.30 (10), p.1695-1701
Hauptverfasser: Mashraqui, Sabir H., Hariharasubrahmanian, Harini
Format: Artikel
Sprache:eng
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Zusammenfassung:3,4-bis(4′-methylphenyl) thienothiophene, the first example of peri-(3,4) diaryl thienothiophene has been synthesized by a sequence involving preparation of ketene dithioacetal, Dieckmann type cyclization, ester hydrolysis and decarboxylation.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397910008087211