Structure and Luminescent Properties of the 4-Arylidene-2-Aryl-5-Oxazolones(Azlactones)In Solution and Crystalline State
Experimental and theoretical evaluations have proven that very low fluorescence quantum yields of azlactones in solution are not caused by an efficient inter system crossing from S 1 *(ππ) to T*(nπ) states, but rather from solvation and steric effects, that result in non-planarity of the molecular s...
Gespeichert in:
Veröffentlicht in: | Spectroscopy letters 1999-07, Vol.32 (4), p.553-569 |
---|---|
Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Experimental and theoretical evaluations have proven that very low fluorescence quantum yields of azlactones in solution are not caused by an efficient inter system crossing from S
1
*(ππ) to T*(nπ) states, but rather from solvation and steric effects, that result in non-planarity of the molecular system. High fluorescence quantum yields in the solid state are attributed to the planarity of the azlactone molecule upon packing into the crystal lattice. Supporting evidence was found upon observation of the excited state proton transfer (ESIPT) bands of fluorescence emissions of o-hydroxyarylidene derivatives. The photoinstability of azlactones in liquid states are attributed to photochemical E-Z isomerization and cleavage of the hetero ring α to the carbonyl group. |
---|---|
ISSN: | 0038-7010 1532-2289 |
DOI: | 10.1080/00387019909350006 |