Short-time diffusion of anisotropic particles in suspension-A perturbative approach
We combine the perturbation approach due to Brenner with the induced force formalism developed by Mazur and coworkers to obtain expressions for the friction and mobility tensors for a suspension of deformed spheres. Specializing to spheroids, we show that our general expressions reduce to previously...
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Veröffentlicht in: | Molecular physics 1991-12, Vol.74 (6), p.1195-1207 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | We combine the perturbation approach due to Brenner with the induced force formalism developed by Mazur and coworkers to obtain expressions for the friction and mobility tensors for a suspension of deformed spheres. Specializing to spheroids, we show that our general expressions reduce to previously known results both for an isolated particle and for a pair of particles. Furthermore it appears that the first-order perturbation treatment gives surprisingly accurate results even for large deformations from a spherical geometry. Finally we use the renormalized density fluctuation method due to Beenakker and Mazur to calculate the ensemble average of the one particle mobility over a wide range of particle volume fractions. |
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ISSN: | 0026-8976 1362-3028 |
DOI: | 10.1080/00268979100102901 |