Short-time diffusion of anisotropic particles in suspension-A perturbative approach

We combine the perturbation approach due to Brenner with the induced force formalism developed by Mazur and coworkers to obtain expressions for the friction and mobility tensors for a suspension of deformed spheres. Specializing to spheroids, we show that our general expressions reduce to previously...

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Veröffentlicht in:Molecular physics 1991-12, Vol.74 (6), p.1195-1207
Hauptverfasser: Treloar, R.L., Masters, A.J.
Format: Artikel
Sprache:eng
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Zusammenfassung:We combine the perturbation approach due to Brenner with the induced force formalism developed by Mazur and coworkers to obtain expressions for the friction and mobility tensors for a suspension of deformed spheres. Specializing to spheroids, we show that our general expressions reduce to previously known results both for an isolated particle and for a pair of particles. Furthermore it appears that the first-order perturbation treatment gives surprisingly accurate results even for large deformations from a spherical geometry. Finally we use the renormalized density fluctuation method due to Beenakker and Mazur to calculate the ensemble average of the one particle mobility over a wide range of particle volume fractions.
ISSN:0026-8976
1362-3028
DOI:10.1080/00268979100102901