The Hall effect in dilute ionic solutions

We study the Hall effect for ions in dilute electrolyte solutions by use of a continuum model and hydrodynamic equations that involve electric and magnetic force terms. We find that the problem is simplified by viewing the situation from the rest frame of a moving ion. This allows us to correct a ca...

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Veröffentlicht in:	Molecular physics 1990-05, Vol.70 (1), p.119-128
Hauptverfasser:	Kroh, H.J., Felderhof, B.U.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Electrochemistry Electrodes: preparations and properties Exact sciences and technology General and physical chemistry
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	We study the Hall effect for ions in dilute electrolyte solutions by use of a continuum model and hydrodynamic equations that involve electric and magnetic force terms. We find that the problem is simplified by viewing the situation from the rest frame of a moving ion. This allows us to correct a calculation that we have presented earlier. We find that for stick boundary conditions the Lorentz force on an ion in a strongly polar liquid is reduced by about 44%.
ISSN:	0026-8976 1362-3028
DOI:	10.1080/00268979000100881