Primary Radical Termination in Vinyl Chloride Polymerization

The rate of vinyl chloride polymerization initiated by doubly labeled benzoyl peroxide ('H in the phenyl ring and 14 C in the carboxyl group) in dichloroethane solution was measured by a dilatometric method. The relative significance of primary radical termination in polymerization is examined...

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Veröffentlicht in:	Journal of macromolecular science. Chemistry 1983-10, Vol.20 (7), p.711-722
1. Verfasser:	Okieimen, Ebhodaghe F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Exact sciences and technology Organic polymers Physicochemistry of polymers Polymerization Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The rate of vinyl chloride polymerization initiated by doubly labeled benzoyl peroxide ('H in the phenyl ring and 14 C in the carboxyl group) in dichloroethane solution was measured by a dilatometric method. The relative significance of primary radical termination in polymerization is examined by kinetic analysis of the polymerization rate data and analysis of the polymer samples recovered at 10% conversion for combined initiator fragments.
ISSN:	0022-233X 2332-4082
DOI:	10.1080/00222338308061803