Aqueous Polymerization of Acrylamide Initiated by Ce(lV)-Thioglycolic Acid Redox System

The aqueous polymerization of acrylamide initiated by the redox system Ce(1V)-thioglycolic acid has been studied at 35 ± 0.2°C. The pH measurement shows that a 1:1 metal:ligand complex is formed between Ce(IV) and thioglycolic acid (TGA). The rate of polymerization is given by R P =K[M]1.08[Ce 4+ ]...

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Veröffentlicht in:Journal of macromolecular science. Chemistry 1981-08, Vol.16 (3), p.601-613
Hauptverfasser: Misra, G. S., Dubey, G. P.
Format: Artikel
Sprache:eng
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