Suspension Polymerization of Vinyl Chloride with Programmed Temperature: Morphological Characteristics and Thermal Stability of Polyvinyl Chloride

Polyvinyl chloride) obtained by intermittent polymerization in suspension with temperature programming, has been characterized from the point of view of morphological properties and of thermal stability. The data have been compared with the values of the morphological characteristics and thermal stability for the PVC samples obtained under identical polymerization conditions, but at constant temperature. The polyvinyl chloride) obtained by polymerization with temperature programming has the same properties as the polyvinyl chloride) obtained by simple polymerization at constant temperature, with an identical average molecular weight. However, the former polymer shows improved thermal stability, as well as a decrease in the volumetric properties.