New α-trifluoromethyl-substituted α-amino phosphonates

New α-trifluoromethyl-substituted α-amino phosphonates

The title α-amino phosphonates with orthogonal protective groups (Cbz/OMe, OEt) were obtained on addition of C-nucleophiles to highly electrophilic imines PG–N=C(CF 3)P(O)(OR) 2.

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Veröffentlicht in:Mendeleev communications 2000, Vol.10 (5), p.192-192
Hauptverfasser: Osipov, Sergey N., Artyushin, Oleg I., Kolomiets, Alexey F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The title α-amino phosphonates with orthogonal protective groups (Cbz/OMe, OEt) were obtained on addition of C-nucleophiles to highly electrophilic imines PG–N=C(CF 3)P(O)(OR) 2.
ISSN:0959-9436
DOI:10.1070/MC2000v010n05ABEH001339