An unusually fast nucleophilic addition of amidoximes to acetylene

An unusually fast nucleophilic addition of amidoximes to acetylene

The addition of amidoximes to acetylene in the presence of the KOH–DMSO superbase system afforded O-vinylamidoximes in 26–59% yields.

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Veröffentlicht in:Mendeleev communications 2000, Vol.10 (1), p.29-30
Hauptverfasser: Trofimov, Boris A., Schmidt, Elena Yu, Mikhaleva, Al’bina I., Vasil’tsov, Alexander M., Afonin, Andrey V.
Format: Artikel
Sprache:eng
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Zusammenfassung:The addition of amidoximes to acetylene in the presence of the KOH–DMSO superbase system afforded O-vinylamidoximes in 26–59% yields.
ISSN:0959-9436
DOI:10.1070/MC2000v010n01ABEH001217