An investigation of potassium μ-oxobis[pentachlororuthenium(IV)] in hydrochloric acid solution under microwave irradiation

An investigation of potassium μ-oxobis[pentachlororuthenium(IV)] in hydrochloric acid solution under microwave irradiation

A study of the ruthenium(IV) and (III) species in HCl solution under microwave irradiation shows a decrease in hydrolysis time, depolymerisation and reduction of ruthenium(IV) to ruthenium(III) by an order of magnitude, as compared with conventional heating of solutions in a boiling water bath.

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Veröffentlicht in:Mendeleev communications 1998, Vol.8 (3), p.95-96
Hauptverfasser: Nesterov, Aleksandr A., Bashilov, Aleksandr V., Runov, Valentin K., Kuz’min, Nikolai M.
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Sprache:eng
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Zusammenfassung:A study of the ruthenium(IV) and (III) species in HCl solution under microwave irradiation shows a decrease in hydrolysis time, depolymerisation and reduction of ruthenium(IV) to ruthenium(III) by an order of magnitude, as compared with conventional heating of solutions in a boiling water bath.
ISSN:0959-9436
DOI:10.1070/MC1998v008n03ABEH000920