Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

Electrolysis of malonate and alkylidenemalonates in an undivided cell in methanol in the presence of sodium bromide or sodium iodide as mediators leads to substituted 1,1,2,2-cyclopropanetetracarboxylates in 80–95% substance and 60–75% current yield.

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Veröffentlicht in:Mendeleev communications 1998, Vol.8 (1), p.15-16
Hauptverfasser: Elinson, Michail N., Feducovich, Sergey K., Bushuev, Sergey G., Zakharenkov, Alexander A., Pashchenko, Denis V., Nikishin, Gennady I.
Format: Artikel
Sprache:eng
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Zusammenfassung:Electrolysis of malonate and alkylidenemalonates in an undivided cell in methanol in the presence of sodium bromide or sodium iodide as mediators leads to substituted 1,1,2,2-cyclopropanetetracarboxylates in 80–95% substance and 60–75% current yield.
ISSN:0959-9436
DOI:10.1070/MC1998v008n01ABEH000893