The interaction of 2,5-diphenyl-3,3,4,4-tetracyanopyrrolidine with vinyl ketones

The interaction of 2,5-diphenyl-3,3,4,4-tetracyanopyrrolidine with vinyl ketones

In the presence of an equimolar amount of triethylamine, 2,5-diphenyl-3,3,4,4-tetracyanopyrrolidine 1 reacts with vinyl ketones 3 to give l-amino-5-acyl-2,3,3-tricyano-5-[phenyl(benzylidenamino)methyl]cyclopent-l-enes 6; the structure of molecule 6b has been determined by an X-ray study of the monoc...

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Veröffentlicht in:Mendeleev communications 1996, Vol.6 (3), p.111-112
Hauptverfasser: Nasakin, Oleg E., Lyshchikov, Anatolii N., Lukin, Petr M., Kayukov, Yakov S., Sorho, Siaka, Khrustalev, Viktor N., Struchkov, Yurii T., Urman, Yakov G.
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Sprache:eng
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Zusammenfassung:In the presence of an equimolar amount of triethylamine, 2,5-diphenyl-3,3,4,4-tetracyanopyrrolidine 1 reacts with vinyl ketones 3 to give l-amino-5-acyl-2,3,3-tricyano-5-[phenyl(benzylidenamino)methyl]cyclopent-l-enes 6; the structure of molecule 6b has been determined by an X-ray study of the monocrystal.
ISSN:0959-9436
DOI:10.1070/MC1996v006n03ABEH000603