A Novel trans-1,2-Dimethyldiaziridine–Silver Nitrate Complex: Synthesis and Molecular and Crystal Structure

trans-1,2-Dimethyldiaziridine 1 reacts with AgNO3 yielding a stable complex 2(1:1 ratio); according to X-ray analysis silver ions are coordinated on the lone pairs of the diaziridine nitrogen atoms, and together with molecules of 1 of the opposite configuration form polymer chains.

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Veröffentlicht in:Mendeleev communications 1995, Vol.5 (6), p.218-219
Hauptverfasser: Shustov, Gennadii V., Zolotoi, Alexander B., Konovalikhin, Sergei V., Atovmyan, Lev O., Kostyanovsky, Remir G.
Format: Artikel
Sprache:eng
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Zusammenfassung:trans-1,2-Dimethyldiaziridine 1 reacts with AgNO3 yielding a stable complex 2(1:1 ratio); according to X-ray analysis silver ions are coordinated on the lone pairs of the diaziridine nitrogen atoms, and together with molecules of 1 of the opposite configuration form polymer chains.
ISSN:0959-9436
DOI:10.1070/MC1995v005n06ABEH000533