An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts

An Unusually Easy Oxidative Dequaternization of N-Alkyl-1,2,4-triazinium Salts

Unusually easy dequaternization has been found to occur on treatment of 1-alkyl-3-morpholino-5-phenyl-1,2,4-triazinium iodides with triethylamine in alcohol or acetone solutions at room temperature; a plausible reaction mechanism has been advanced on the basis of NMR and kinetic studies.

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Veröffentlicht in:Mendeleev communications 1995, Vol.5 (3), p.104-105
Hauptverfasser: Chupakhin, Oleg N., Rudakov, Boris V., McDermott, Padraig, Alexeev, Sergey G., Charushin, Valery N., Hegarty, Frank
Format: Artikel
Sprache:eng
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Zusammenfassung:Unusually easy dequaternization has been found to occur on treatment of 1-alkyl-3-morpholino-5-phenyl-1,2,4-triazinium iodides with triethylamine in alcohol or acetone solutions at room temperature; a plausible reaction mechanism has been advanced on the basis of NMR and kinetic studies.
ISSN:0959-9436
DOI:10.1070/MC1995v005n03ABEH000478