Palladium-catalysed Carbonylation of Halogenoalkynes to Alkynylcarboxylic Acid Esters under Mild Conditions

Palladium-catalysed carbonylation reactions of bromoalkynes and iodoalkynes, as well as the carbonylation reaction of σ-alkynylpalladium(II) complexes under atmospheric pressure of carbon monoxide lead to formation of alkynylcarboxylic acid esters.

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Veröffentlicht in:Mendeleev communications 1995, Vol.5 (1), p.3-4
Hauptverfasser: Zung, Ton T., Bruk, Lev G., Temkin, Oleg N., Malashkevich, Aleksandr V.
Format: Artikel
Sprache:eng
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Zusammenfassung:Palladium-catalysed carbonylation reactions of bromoalkynes and iodoalkynes, as well as the carbonylation reaction of σ-alkynylpalladium(II) complexes under atmospheric pressure of carbon monoxide lead to formation of alkynylcarboxylic acid esters.
ISSN:0959-9436
DOI:10.1070/MC1995v005n01ABEH000431