Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

Two Alternative Pathways for the Interaction of Hexacyanocyclopropane with Nucleophiles

Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 w...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Mendeleev communications 1994, Vol.4 (5), p.185-186
Hauptverfasser: Nasakin, Oleg E., Lukin, Petr M., Vershinin, Evgenii V., Lindeman, Sergei V., Struchkov, Yurii T.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Methanol molecules add to the cyano groups of hexacyanocyclopropane 1 in the presence of sodium methylate to give 1,4-adduct 2. The interaction of 1 with N-methylpyridinium iodide leads to opening of the cyclopropane ring and to the formation of propenide 3 and iodine cyanide 4; the structure of 2 was established by an X-ray crystallographic study.
ISSN:0959-9436
DOI:10.1070/MC1994v004n05ABEH000407