Absolute Configuration of 1,4-Dialkyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-dione Enantiomers

The correlation of the Cotton effect sign of the n → π* transition with the cage structure chirality and the absolute configuration of 1,4-dialkyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-diones has been established.

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Veröffentlicht in:Mendeleev communications 1994, Vol.4 (3), p.97-99
Hauptverfasser: Vystorop, Igor V., Shustov, Gennadii V., Rauk, Arvi, Kostyanovsky, Remir G.
Format: Artikel
Sprache:eng
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Zusammenfassung:The correlation of the Cotton effect sign of the n → π* transition with the cage structure chirality and the absolute configuration of 1,4-dialkyl-2,5-dioxabicyclo[2.2.1]heptane-3,6-diones has been established.
ISSN:0959-9436
DOI:10.1070/MC1994v004n03ABEH000366