Organic Electron Carriers in the Electrochemical Synthesis of Metal Carbonyls

Organic Electron Carriers in the Electrochemical Synthesis of Metal Carbonyls

Homogeneous reduction of Ni II, Fe II and Co II ions by anion-radicals of organic compounds in the presence of carbon monoxide, in a mixture of acetonitrile and benzene (3:1) under normal conditions, leads to metal carbonyls (Ni, Fe) and carbonyl metal anions (Co).

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Veröffentlicht in:Mendeleev communications 1993, Vol.3 (5), p.208-209
Hauptverfasser: Yanilkin, Vitalii V., Garifullin, Bulat M., Nigmadzhanov, Farid F., Titova, Zoya S., Kargin, Yurii M.
Format: Artikel
Sprache:eng
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Zusammenfassung:Homogeneous reduction of Ni II, Fe II and Co II ions by anion-radicals of organic compounds in the presence of carbon monoxide, in a mixture of acetonitrile and benzene (3:1) under normal conditions, leads to metal carbonyls (Ni, Fe) and carbonyl metal anions (Co).
ISSN:0959-9436
DOI:10.1070/MC1993v003n05ABEH000295