Ehrenfest modeling of cavity vacuum fluctuations and how to achieve emission from a three-level atom

A much-needed solution for the efficient modeling of strong coupling between matter and optical cavity modes is offered by mean-field mixed quantum–classical dynamics, where a classical cavity field interacts self-consistently with quantum states of matter through Ehrenfest’s theorem. We previously...

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Veröffentlicht in:The Journal of chemical physics 2023-12, Vol.159 (22)
Hauptverfasser: Hsieh, Ming-Hsiu, Krotz, Alex, Tempelaar, Roel
Format: Artikel
Sprache:eng
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Zusammenfassung:A much-needed solution for the efficient modeling of strong coupling between matter and optical cavity modes is offered by mean-field mixed quantum–classical dynamics, where a classical cavity field interacts self-consistently with quantum states of matter through Ehrenfest’s theorem. We previously introduced a modified mean-field approach, referred to as decoupled mean-field (DC-MF) dynamics, wherein vacuum fluctuations of the cavity field are decoupled from the quantum-mechanical ground state as a means to resolve an unphysical drawing of energy from the vacuum fluctuations by a two-level atom. Here, we generalize DC-MF dynamics for an arbitrary number of (nondegenerate) atomic levels and show that it resolves an unphysical lack of emission from a three-level atom predicted by conventional mean-field dynamics. We furthermore show DC-MF to provide an improved description of reabsorption and (resonant) two-photon emission processes.
ISSN:0021-9606
1089-7690
DOI:10.1063/5.0175145