Extension of the statistical mechanics of equilibrium to noncommutative constraints

A formula similar to the Gibbs canonical and grand canonical ensembles is proven for the ensemble of maximal entropy among those ensembles of common mean values of possibly n o n c o m m u t i n g operators. This is done over a Hilbert space of finite dimension Δ. A partition matrix Π becomes import...

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Veröffentlicht in:Journal of mathematical physics 1976-05, Vol.17 (5), p.753-755
1. Verfasser: Lubkin, Elihu
Format: Artikel
Sprache:eng
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Zusammenfassung:A formula similar to the Gibbs canonical and grand canonical ensembles is proven for the ensemble of maximal entropy among those ensembles of common mean values of possibly n o n c o m m u t i n g operators. This is done over a Hilbert space of finite dimension Δ. A partition matrix Π becomes important; the partition function Z=TrΠ displaces Π in the thermodynamics only in the commutative case. Generalization to Δ infinite is discussed informally.
ISSN:0022-2488
1089-7658
DOI:10.1063/1.522986