The role of anharmonicity in the systems with spin crossover

The role of anharmonicity in the systems with spin crossover

The model describing the effect of anharmonicity on the spin-crossover properties of Fe(II) complex is proposed. It is shown that anharmonicity can be one of the important factors controlling the magnetic transitions of the low-spin high-spin type.

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Bibliographische Detailangaben
Veröffentlicht in:Low temperature physics (Woodbury, N.Y.) N.Y.), 2016-06, Vol.42 (6), p.505-512
Hauptverfasser: Shelest, V. V., Khristov, A. V., Levchenko, G. G.
Format: Artikel
Sprache:eng
Schlagworte:
Anharmonicity
Crossovers
Magnetic transitions
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Zusammenfassung:The model describing the effect of anharmonicity on the spin-crossover properties of Fe(II) complex is proposed. It is shown that anharmonicity can be one of the important factors controlling the magnetic transitions of the low-spin high-spin type.
ISSN:1063-777X
1090-6517
DOI:10.1063/1.4954782