Dielectric performance of polymer-based composites containing core-shell Ag@TiO2 nanoparticle fillers
This paper reports composites prepared by embedding core-shell Ag@TiO2 fillers into polytetrafluoroethylene. Ag nanoparticles were homogeneously coated with TiO2, to give a shell thickness of approximately ∼8–10 nm. The composite containing Ag@TiO2 nanoparticles with rutile shells exhibited better d...
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Veröffentlicht in: | Applied physics letters 2016-02, Vol.108 (7) |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | This paper reports composites prepared by embedding core-shell Ag@TiO2 fillers into polytetrafluoroethylene. Ag nanoparticles were homogeneously coated with TiO2, to give a shell thickness of approximately ∼8–10 nm. The composite containing Ag@TiO2 nanoparticles with rutile shells exhibited better dielectric properties than the composite containing Ag@TiO2 nanoparticles with anatase shells. The relative permittivity (εr) of the composite containing 70 vol. % filler was approximately 240 at 100 Hz, which was more than 100 times higher than that of pure polytetrafluoroethylene (εr = 2.1). An effective medium percolation theory model is used to account for the dielectric constant of the composite. |
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ISSN: | 0003-6951 1077-3118 |
DOI: | 10.1063/1.4942096 |