A note on the green dyadic calculation of the decay rates for admolecules at multiple planar interfaces

The Green dyadic formulation for calculating classical decay rates of admolecules at multiple planar interfaces first published by Chance, Prock and Silbey is reexamined. It is pointed out that, for the case of fluorescing molecules sandwiched between a system of super- and substrate interfaces, the...

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Veröffentlicht in:The Journal of chemical physics 1999-01, Vol.110 (4), p.2189-2194
Hauptverfasser: Hartman, R. L., Cohen, S. M., Leung, P. T.
Format: Artikel
Sprache:eng
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Zusammenfassung:The Green dyadic formulation for calculating classical decay rates of admolecules at multiple planar interfaces first published by Chance, Prock and Silbey is reexamined. It is pointed out that, for the case of fluorescing molecules sandwiched between a system of super- and substrate interfaces, the original formalism requires significant modifications in order to lead to results consistent with those obtained from the Sommerfeld radiation theory.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.477830