Quadrupolar spin relaxation of N14 in NNO in collisions with various molecules

Quadrupolar spin relaxation of N14 in NNO in collisions with various molecules

Spin-lattice relaxation times were measured for the N14 relaxation of both N14 nuclei in NNO in the pure gas and in mixtures with the following buffer gases; Ar, Kr, Xe, HCl, N2, CO, CO2, CH4, CF4, and SF6. Effective collision cross sections for molecular reorientation of NNO in collisions with thes...

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Veröffentlicht in:The Journal of chemical physics 1998-12, Vol.109 (23), p.10227-10237
Hauptverfasser: Jameson, Cynthia J., ter Horst, Marc A., Jameson, A. Keith
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container_issue 23
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container_title The Journal of chemical physics
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creator Jameson, Cynthia J.
ter Horst, Marc A.
Jameson, A. Keith
description Spin-lattice relaxation times were measured for the N14 relaxation of both N14 nuclei in NNO in the pure gas and in mixtures with the following buffer gases; Ar, Kr, Xe, HCl, N2, CO, CO2, CH4, CF4, and SF6. Effective collision cross sections for molecular reorientation of NNO in collisions with these ten molecules are obtained, as a function of temperature, directly from the measured relaxation times of the end N14 nucleus in the NNO molecule.
doi_str_mv 10.1063/1.477718
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title Quadrupolar spin relaxation of N14 in NNO in collisions with various molecules
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