Quadrupolar spin relaxation of N14 in NNO in collisions with various molecules
Spin-lattice relaxation times were measured for the N14 relaxation of both N14 nuclei in NNO in the pure gas and in mixtures with the following buffer gases; Ar, Kr, Xe, HCl, N2, CO, CO2, CH4, CF4, and SF6. Effective collision cross sections for molecular reorientation of NNO in collisions with thes...
Gespeichert in:
Veröffentlicht in: | The Journal of chemical physics 1998-12, Vol.109 (23), p.10227-10237 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Spin-lattice relaxation times were measured for the N14 relaxation of both N14 nuclei in NNO in the pure gas and in mixtures with the following buffer gases; Ar, Kr, Xe, HCl, N2, CO, CO2, CH4, CF4, and SF6. Effective collision cross sections for molecular reorientation of NNO in collisions with these ten molecules are obtained, as a function of temperature, directly from the measured relaxation times of the end N14 nucleus in the NNO molecule. |
---|---|
ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.477718 |