First spectroscopic evidence for molecular HCl on a liquid surface with sum frequency generation
Sum frequency generation spectroscopy has been used to obtain the vibrational spectrum of HCl on the surface of a liquid. HCl was studied on the surface of 96 wt % H2SO4, 12 M HCl solution, liquid HCl and glass, of which only liquid HCl produces a resonant signal. Implications for the form of HCl on...
Gespeichert in:
| Veröffentlicht in: | The Journal of chemical physics 1998-06, Vol.108 (23), p.9817-9820 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| Zusammenfassung: | Sum frequency generation spectroscopy has been used to obtain the vibrational spectrum of HCl on the surface of a liquid. HCl was studied on the surface of 96 wt % H2SO4, 12 M HCl solution, liquid HCl and glass, of which only liquid HCl produces a resonant signal. Implications for the form of HCl on surfaces and the reactions in the atmosphere are discussed. |
|---|---|
| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.476456 |