Auger decay of the dissociating core-excited states in the HCl and DCl molecules
High-resolution Auger electron spectra from the decay of the Cl 2p→σ* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5σ2π)4σ* and Cl (3s3p)6 states, respectively. Auger line shapes, as af...
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| Veröffentlicht in: | The Journal of chemical physics 1996-03, Vol.104 (12), p.4475-4480 |
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| container_end_page | 4480 |
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| container_issue | 12 |
| container_start_page | 4475 |
| container_title | The Journal of chemical physics |
| container_volume | 104 |
| creator | Kukk, E. Aksela, H. Sairanen, O.-P. Aksela, S. Kivimäki, A. Nõmmiste, E. Ausmees, A. Kikas, A. Osborne, S. J. Svensson, S. |
| description | High-resolution Auger electron spectra from the decay of the Cl 2p→σ* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5σ2π)4σ* and Cl (3s3p)6 states, respectively. Auger line shapes, as affected by the molecular dissociation, are studied by comparing the experiment with the results of Monte-Carlo computer simulations based on a semiclassical model. |
| doi_str_mv | 10.1063/1.471542 |
| format | Article |
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The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5σ2π)4σ* and Cl (3s3p)6 states, respectively. Auger line shapes, as affected by the molecular dissociation, are studied by comparing the experiment with the results of Monte-Carlo computer simulations based on a semiclassical model.</abstract><doi>10.1063/1.471542</doi><tpages>6</tpages></addata></record> |
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| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1996-03, Vol.104 (12), p.4475-4480 |
| issn | 0021-9606 1089-7690 |
| language | eng |
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| source | AIP Digital Archive |
| title | Auger decay of the dissociating core-excited states in the HCl and DCl molecules |
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