Auger decay of the dissociating core-excited states in the HCl and DCl molecules
High-resolution Auger electron spectra from the decay of the Cl 2p→σ* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5σ2π)4σ* and Cl (3s3p)6 states, respectively. Auger line shapes, as af...
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Veröffentlicht in: | The Journal of chemical physics 1996-03, Vol.104 (12), p.4475-4480 |
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Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | High-resolution Auger electron spectra from the decay of the Cl 2p→σ* excitation in HCl and DCl have been measured. The spectra are analyzed, separating molecular and atomic features, which are assigned to transitions to the HCl (5σ2π)4σ* and Cl (3s3p)6 states, respectively. Auger line shapes, as affected by the molecular dissociation, are studied by comparing the experiment with the results of Monte-Carlo computer simulations based on a semiclassical model. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.471542 |