Observation of the broadening and shift of the frustrated translation vibrational mode of CO on Cu(001) by high resolution helium atom scattering
The lifetime broadening of the frustrated translation (T) mode parallel to the surface of isolated CO molecules [≲6% of a c(2×2) coverage] chemisorbed on Cu(001) has been studied with high resolution inelastic helium atom scattering as a function of the surface temperature and the parallel momentum...
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Veröffentlicht in: | The Journal of chemical physics 1996-04, Vol.104 (13), p.5311-5316 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The lifetime broadening of the frustrated translation (T) mode parallel to the surface of isolated CO molecules [≲6% of a c(2×2) coverage] chemisorbed on Cu(001) has been studied with high resolution inelastic helium atom scattering as a function of the surface temperature and the parallel momentum transfer. The T excitation peak shows a temperature dependent peak shift and a broadening. The latter is attributed to a quartic anharmonic potential contribution described by a spectroscopic constant χe=−0.0085±0.0008. The extrapolated TS=0 K peak broadening is then γ0=85±5 μeV, corresponding to a vibrational lifetime τ=8±1 ps. We attribute this lifetime to substrate phonon mediated damping and electronic damping. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.471260 |