Infrared spectroscopy, infrared photoconversion, and ultraviolet photodissociation of NO dimers in neon and nitrogen matrices

The nitric oxide dimers isolated in neon or nitrogen matrices have been irradiated in the infrared by selected lines of a cw CO laser and in the UV at 193 nm by an ArF excimer laser. IR excitation of the antisymmetric mode of the cis dimer in neon induces a conversion to a special van der Waals dime...

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Veröffentlicht in:The Journal of chemical physics 1995-05, Vol.102 (20), p.7798-7806
Hauptverfasser: Legay, F., Legay-Sommaire, N.
Format: Artikel
Sprache:eng
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Zusammenfassung:The nitric oxide dimers isolated in neon or nitrogen matrices have been irradiated in the infrared by selected lines of a cw CO laser and in the UV at 193 nm by an ArF excimer laser. IR excitation of the antisymmetric mode of the cis dimer in neon induces a conversion to a special van der Waals dimer. At T
ISSN:0021-9606
1089-7690
DOI:10.1063/1.469033