Photoassociative spectroscopy of 1 g , 0+ u , and 0− g states of Na2

We use photoassociation of ultracold Na to study transitions from free atoms to bound molecules. We obtain rovibrational spectra of the 1g, the 0+u, and, for the first time, the 0−g ‘‘purely long-range’’ state of Na2, all of which dissociate to Na(3 2S1/2)+Na(3 2P3/2).

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Veröffentlicht in:The Journal of chemical physics 1994-08, Vol.101 (3), p.2638-2641
Hauptverfasser: Ratliff, L. P., Wagshul, M. E., Lett, P. D., Rolston, S. L., Phillips, W. D.
Format: Artikel
Sprache:eng
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Zusammenfassung:We use photoassociation of ultracold Na to study transitions from free atoms to bound molecules. We obtain rovibrational spectra of the 1g, the 0+u, and, for the first time, the 0−g ‘‘purely long-range’’ state of Na2, all of which dissociate to Na(3 2S1/2)+Na(3 2P3/2).
ISSN:0021-9606
1089-7690
DOI:10.1063/1.467638